Poly[tetramethylammonium [tri-μ2-formato-κ6O:O′-manganate(II)]]
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چکیده
منابع مشابه
Poly[tetramethylammonium [tri-μ2-formato-κ6 O:O′-manganate(II)]]
In the title compound, {(C4H12N)[Mn(HCO2)3]} n , the Mn(II) atom lies on an inversion centre and is coordinated by O-atom donors from the three double-bridging formate ligands, one of which lies across a crystallographic mirror plane, giving a slightly distorted octahedral coordination sphere. A three-dimensional NaCl-type framework is generated in which the tetra-methyl-ammonium cations, which...
متن کاملPoly[bis(μ2-formato-κ2 O:O′)(quinoxaline-κN)copper(II)]
In the polymeric title copper(II) compound, [Cu(CHO(2))(2)(C(8)H(6)N(2))](n), both formato ligands are O-bidentate anions and act as bridging ligands, creating a planar polymeric arrangement. The slightly distorted square-pyramidal coordination around Cu(II) comprises four O atoms from two different formate anions as the base and a quinoxaline mol-ecule in the apical position.
متن کاملPoly[di-μ2-chlorido-tri-μ2-terephthalato-tetralead(II)]
The title compound, [Pb(4)(C(8)H(4)O(4))(3)Cl(2)](n), consists of a three-dimensional inorganic-organic hybrid framework. The asymmetric unit contains two Pb(2+) cations, one Cl(-) anion and one and a half terephthalate anions, the latter being completed by inversion symmetry. The two Pb(2+) cations are each surrounded by five O atoms and one Cl atom in the form of irregular polyhedra. The cati...
متن کاملPoly[guanidinium [tri-μ-formato-κ6 O:O′-formato-κ2 O,O′-yttrium(III)]]
In the title coordination polymer, {(CH6N3)[Y(CHO2)4]} n , the yttrium(III) ion is coordinated by one O,O-bidentate formate ion and six μ2 bridging formate ions, generating a square-anti-prismatic YO8 coordination polyhedron. The bridging formate ions connect the metal ions into an anionic, three-dimensional network. Charge compensation is provided by guanidinium ions, which inter-act with the ...
متن کاملcatena-Poly[manganese(II)-(μ2-3,5-di-2-pyridyl-1,2,4-triazolato)-μ2-formato]
Owing to the presence of crystallographic twofold rotation axes (site symmetry 2, Wyckoff letters e and f), the asymmetric unit of the title compound, [Mn(C(12)H(8)N(5))(CHO(2))](n), contains one-half of an Mn(II) cation, one-half of a bpt anion (Hbpt is 3,5-di-2-pyridyl-4H-1,2,4-triazole) and one-half of a formate anion. The bpt and formate ligands occupy the same C(2) symmetry, while the Mn(I...
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ژورنال
عنوان ژورنال: Acta Crystallographica Section E Structure Reports Online
سال: 2013
ISSN: 1600-5368
DOI: 10.1107/s1600536813024045